Yutaka Ohno
Tohoku University, Japan
Title: Chemical nanoanalyses of Si grain boundaries towards the fabrication of highfunctional Si solar cells
Biography
Biography: Yutaka Ohno
Abstract
Polycrystalline materials with grain boundaries (GBs), involving excess free energy because of their structural imperfection, can reduce their energy by the nanoscopic structural changes of the GBs via impurity segregation. Those local changes at GBs can stabilize non-equilibrium nanostructures, resulting in the drastic change in the macroscopic properties of those materials. The mechanism of GB segregation is, however, far from being understood due to difficulties in characterizing both crystallographic and chemical properties of the same GB at atomistic levels. We have therefore developed an analytical method to determine the impurity segregation ability on the same GB at the same nanoscopic location by a joint use of atom probe tomography (APT) and scanning transmission electron microscopy (STEM) combined with ab initio calculations, and discussed the segregation mechanism at atomistic levels. Three-dimensional distribution of impurity atoms was systematically determined at the typical large-angle GBs, small-angle GBs, and dislocations on GBs in Si by APT with a high spatial resolution (about 0.4nm), and it was correlated with the atomic stresses around the GBs estimated by ab initio calculations based on atomic-resolution STEM data. It was shown that impurity atoms preferentially segregated at the atomic positions under specific stresses so as to attain a more stable bonding network by reducing the local stresses. For example, the number of segregating oxygen atoms per unit GB area (NGB) is proportional to both the number of the stressed positions per unit GB area (nbc) and the average concentration of oxygen atoms around the GB ([Oi ]) with NGB ~ 50nbc[Oi ].